4,4-Methylenedianiline

4,4-Methylenedianiline

Details
4,4-Methylenedianiline appears as white to yellowish crystals at room temperature. As an important chemical industry intermediate, 4,4-Methylenedianiline is widely used in the production of MDI and HMDI, as well as in polyimide (PI), polyetherimide (PEI), epoxy resin hardeners, bismaleimide resins, and polyurethane (PU) elastomer chain extenders. Products synthesized with 4,4′-Methylenedi-Aniline exhibit excellent mechanical, electrical insulation, heat resistance, radiation resistance, and abrasion resistance properties.
Category
Mda-100
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Description
Technical Parameters

Specifications

 

Structural formula:

MDA1

 

Test Item(s)

Unit

Specification(s)

Test Method(s)

Appearance

-

White or yellowish crystal granules

Visual

Melting Point

≥90.0

93℃

Point apparatus

2,4' -MDA

≤1.0

0.155(A/A)

GC

4,4' -MDA

≥99.0

99.595(A/ A)

GC

 

CAS NO.: 101-77-9

Chemical formula:C13H14N2

Molecular weight:198.26

Packaging: Plastic-lined paper bags: 25 kg/bag;

 

Flexible containers: 450 kg/bag, 500 kg/bag, or customized packaging;

 

GHS Classification

 

Acute Toxicity (Oral) Category 3 Skin Sensitizer Category 1 Germ Cell Mutagen Category 2 Carcinogen Category 1B

Specific Target Organ Toxicity - Single Exposure, Category 1 Specific Target Organ Toxicity - Repeated Exposure, Category2 Harm to aquatic

environment (acute) Category 1

Harm to aquatic environment (long term) Category 1

 

Symbols:

1

 

Signal Words: Danger Hazard Statements:

Toxic if swallowed.

May cause allergic skin reaction. Suspected of causing genetic defects. May cause cancer.Causes damage to organs.May cause damage to organs if through prolong or repeated exposure (inhalation ,oral, liver).High toxic to aquatic life with long lasting effects.

 

Response

 

IF swallowed: Rinse mouth. Immediate medical attention required. IF on skin: Wash affected areas with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. If exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell.Collect spillage timely.

 

Dispose of contents/container in accordance with local/ regional/ national/international regulations.

Product Storage & Handling Guidelines

Storage Requirements: Store in a dry, clean, and well-ventilated warehouse. Avoid exposure to light, heat sources, or direct sunlight to mitigate oxidation risks.

Transportation Precautions: Ensure packaging is secure to prevent leakage. Shield from rain, moisture, and direct sunlight during transit.

4,4-Methylenedianiline has a shelf life of 12 months under recommended storage conditions. Products stored past their expiration date may still be used if test results remain qualified. For safety and environmental details, consult the Material Safety Data Sheet (MSDS) or contact our customer service center.

 

 

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